Crystallochemical characterization of polyoxometalate new minerals
نویسندگان
چکیده
منابع مشابه
synthesis and characterization of some new cyclometalated organoplatinum(ii) complexes containing phosphite ligand
در این تحقیق روشی جهت سنتز یک سری از کمپلکس های پلاتین (ii) حاوی لیگاند های دهنده ی فسفری شامل فسفیت و فسفین ارائه شده است. واکنش پیش ماده ی پلاتین (ii)،trans/cis- [ptcl2(sme2)2] ، با 2 اکی مولار از لیگاند p(oph)3در حلال بنزن کمپلکس1، cis-[ptcl2(p(oph)3)2] را تولید می نماید. جهت سنتز کمپلکس سایکلو متال فسفیتی، کمپلکس 1 با 1 اکی والان واکنشگر ptcl2 در حلال زایلن در شرایط رفلاکس زیر گاز آرگون م...
Crystallochemical Characterization of Magnetic Spinels Prepared from Aqueous Solution
The crystallochemical characterization of magnetic spinels prepared from aqueous solution has been studied primarily by electron microscopy and 5 Fe Mossbauer spectroscopy. . Two synthetic routes investigated : 7Fe have been t : method 1; partial oxidation of Fell solutions " in the presence of NO;; at 100°C, O C , and method 2; reaction of hydrated Fe oxide (ferrihydrite) with Fell ions at roo...
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A cross-linked polyethyleneimine polymer containing the[ZnWZn2(H2O)2(ZnW9O34)2] poly-oxometalate was prepared from branched polyethyleneimine(Mw ) 600), the polyoxometalate, and an-octylamine-epichlorohydrin cross-linking reagent. This catalytic assembly was active for the selectiveoxidation of 2-alkanols to 2-alkanones with aqueous H2O2 with reactions presumably occurring a...
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The reaction of Cl(3)Sn(CH(2))(2)COOCH(3), [H(2)P(2)W(12)O(48)](12-) and WO(4)(2-) in acetate buffer solution led to the hydrolysis of estertin into a carboxyethyltin group and the assembly of a new tetra(organotin)-decorated boat-like polyoxometalate.
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Fluorescent nano-/microrods of the polyoxometalate (POM) K4H[Eu(α-SiW11O39)(H2O)2] · 17H2O were obtained in aqueous solution by a conventional synthesis method. The nano-/microrods have been characterized by elemental analysis and FT-IR, UV/Vis, and TG-DTA data, and their morphology was examined by ESEM-FEG, showing that the average ratio of diameter to length is 1 : 20. The obtained nano-/micr...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section A Foundations and Advances
سال: 2017
ISSN: 2053-2733
DOI: 10.1107/s2053273317089793